MATS Timing and Technology Options” discussed in Hot Topic on August 7, 2014

 

The webinar was crafted to assist power plants dealing with meeting the new Mercury and Air Toxic Standards (MATS rules). The challenge is that the best solution for mercury removal may not be  the best solution for removing the necessary quantities of acid gases and fine particulate. The best air pollution solution may not be the best environmental solution when water and solid waste aspects are considered. So you need to travel back and forth between technology solutions to find the one most appropriate to your needs. The McIlvaine system for doing this is equivalent to a trip using GPS and is labeled Global Decisions Positioning System (GDPS).

 

This GDPS takes you back and forth through a number of free websites each focused on one of these decision areas Continuous Analyses. The webinar referenced these websites and displays.

The webinar included insights from experts on the latest developments and how they may affect decision making.   Those experts included:

 

§   Gifford  Broderick, Combustion Components Associates, Inc

§   Kevin Crosby, Technical Director, The Avogadro Group, LLC 

§   Paul Barilla, P.E., Consultant 

 

The large number of uncertainties makes it difficult to determine a course of action to deal with the Mercury and Air Toxics Standard.  You may initially reject plant retirement as a solution but as the cost of the compliance options mount, you may have to revisit that decision. You may make a tentative decision to use wet scrubbing but then find that the water pollution control costs make this unattractive.  A dry scrubber may look attractive until you evaluate the restrictions on flyash sales and landfill costs.  The result is that the MATS decision process is complex and can be likened to a maze. This webinar provided the equivalent of a GPS system to negotiate the maze. It could be called the MATS Global Decisions Positioning System (GDPS).

 

MATS GDPS

 

 

 

 

 

Plant retirement is the first consideration.  Capital investment to meet MATS will be substantial.  An old plant may only be valued at $500/kW. Expenditures to meet MATS may in an extreme case be $400/kW.  So you are nearly doubling your investment. Will it be worthwhile? Here are some of the factors to be considered. 

 

 

  1st Decision Tree Stop:  Plant Retirement Decision Tree

 

 

Factors Favoring Retirement

Factors Favoring Retention

Excessive Regulatory Cost

Alternative

Options

Factors Favoring

MATS Investment

MATS

GTCC

Demand Growth

CCR  And Effluent

Wind

High Gas Prices

Ambient Air Quality

Solar

Technology to Make MATS Lower Cost

Carbon Tax

Demand Reduction

Marginal Coal Plants Retired Instead

 

Another option is to convert to natural gas-firing in your existing boiler. Gifford Broderick, Combustion Components Associates, addressed this option. Converting to natural gas-firing could cost less than $ 100/kW. This compares favorably to the cost of scrubbers and other air pollution control to upgrade the coal-fired power plant. It is also 1/10 the cost of a new GTCC plant.

 

This is the initial stop but will need to be revisted as the cost of the MATS compliance option is further developed.  The decision to upgrade to meet MATS has to start with particulate control. The MATS rule allows the operator to either meet a very low PM2.5 limit or to separately measure toxic metals. Due to the difficulty in measuring toxic metals virtually all plants will opt for the lower particulate limit.

 

        Decision Tree Stop:  Start immediately with a monitoring program

 

You need to determine what measurements need to be made in advance of an investment decision and then what measurements will be needed to avoid violations when the solution is up and operating.  Kevin Crosby, Technical Director, The Avogadro Group, LLC, addressed the monitoring needs  at all points along the way. There are continuous monitoring and periodic testing options for toxic metals, mercury and HCl. So these approaches should be determined in advance.

 

Due to some oversights in the mercury monitoring rules, the selection of  a monitoring method may affect the equipment choices. If you use sorbent traps rather than mercury CEMS you may need better particulate control. The reasoning is that the sorbent traps pick up particulate mercury. Kevin addressed this observation by saying that a filter prior to the sorbent trap would eliminate the measurement of particulate mercury in the sorbent trap itself. However, if particulate mercury is substantial it would need to be addressed.

 

       2nd Decision Tree Stop:  Particulate Decision

 

Keep the Existing Precipitator

Change to Fabric Filter

New downstream scrubber will obtain additional particulate removal.

Can be inserted into existing precipitator casing.

Can add a wet ESP after the scrubber.

Will be used in conjunction with dry scrubbing or DSI.

Upgrade the existing precipitator.

Reduce the sorbent injection for mercury control.

 

Hot Gas Filtration for all MATS requirements—See McIlvaine Website  Hot Gas Filters - Continuous Analyses

 

There are proposed regulations in the U.S. dealing with coal combustion residues and effluent water quality.  Dry scrubbers create combustion residues and wet scrubbers create effluent.  So MATS decisions have to take these future standards into consideration.

 

 

3rd Decision Tree Stop:  Solids Regulations and Flyash Salability

 

Choice of dry scrubbers with fabric filter for both particulate control and SO2 capture will result in unsalable flyash.

Activated carbon in ash may make flyash unsalable.

New CCR regulations can impact the MACT choice.

Ramifications of CCR and effluent analyzed on McIlvaine website:

CCR and Effluent - Continuous Analyses

 

 

 

4th Decision Tree StopNOx Control Technology

 

Many plants will have to meet new NOx limits as a result of federal or state rules. SCR is a big investment and takes up lots of space.  So you will want to integrate NOx and MATS decisions

NOx catalysts can also oxidize mercury and allow the wet scrubber to capture more mercury.

Hot gas filtration for all MATS requirements—See McIlvaine Website 

Hot Gas Filters - Continuous Analyses

 

There is a requirement in MATS to reduce HCl. EPA says much of the benefit of MATS is the SO2 reduction which will coincidently take place with HCl capture.

 

 

5th Decision Tree Stop:  Select FGD Type and Reagent

 

MATS HCl Capture Table Low Sulfur Coal and Use Existing Precipitator

 

 

a

FGD Type

b

Reagent

c

Efficiency

d

Performance

e

Maintenance

f

Capital Cost

g

Operation Cost

1

Wet

Limestone

High

Reliable

Medium

High

Low

2

Wet

Lime

High

Reliable

Low

Medium

Medium

3

Spray Drier

Hydrated Lime

High but limits

Atomizer Changes

Medium

Medium

Medium

4

Circulating Dry

Hydrated Lime

High

Reliable

Medium

Medium

Medium

5

DSI

Hydrated Lime

Medium

Qualified

Low

Low

High

6

DSI

High Reactivity Hydrated Lime

High

Qualified

Low

Low

High

7

DSI

Trona

High

TBO*

TBO*

Medium

High

8

DSI

Double Alkali

High

TBO*

Low

Low

High

9

HCl Prescrubber

Water

High

TBO*

Low

Medium

Low

*To be determined

 

One McIlvaine website covers the wet option Wet Calcium FGD - Continuous Analyses

 

Another McIlvaine website covers DSI, spray driers, and circulating dry scrubbers  Dry Scrubbing - Continuous Analyses

 

Hot gas filtration for all MATS requirements—See McIlvaine Website Hot Gas Filters - Continuous Analyses

 

 

6th Decision Tree Stop - Air Toxics

 

Three air toxics addressed in MATS are mercury, HCl and toxic metals. The HCl reduction is tied into the FGD.  The toxic metals will be removed by the particulate collector. So that leaves mercury as the remaining contaminant to address.  McIlvaine has covered all the options for mercury reduction at Mercury Removal - Continuous Analyses.

 

Individual presentations follow:

 

MATS Timing and Technology Options Webinar - Hot Topic Hour August 7, 2014

The webinar was crafted to assist power plants dealing with meeting the new Mercury and Air Toxic Standards (MATS rules).

Revision Date: 8/7/2014

MATS Emission Testing and Monitoring Requirements, by Kevin Crosby, Montrose Environmental (The Avogadro Group) - Hot Topic Hour August 7, 2014

Kevin addressed monitoring needs. There are continuous monitoring and periodic testing options for toxic metals, mercury and HCl.

Revision Date: 8/7/2014


Converting to Natural Gas for MATs Compliance by R. Gifford Broderick, Combustion Components Associates - Hot Topic Hour August 7, 2014

Giff Broderick addressed the option of converting to natural gas-firing in an existing boiler.

Revision Date: 8/7/2014