Lots of choices for Demineralization and Degasification of HRSG Water - Hot Topic Thursday, August 28

 

The early birds heard some good but unfortunately unrecorded discussions between Bob Markle of Membrana and Michael Snow of SnowPure relative to some of the advantages of combining membrane contactors and EDI.  The comments and presentations when we started recording were of similarly high quality as the focus was on the choices that need to be made by purchasers and operators of ultrapure water systems for gas turbine combined cycle power. The free site, which is the basis of the continuing discussions, is Degasification and Demineralization.

 

Overview by Bob McIlvaine of McIlvaine

 

Degasification and Demineralization is a continually updated website to empower decision making by plant owners. It is also part of Gas Turbine and Combined Cycle Decisions. The types of issues which need to be addressed are EDI vs. IE, FD deaerators vs. membrane contactors, and nitrogen vs. vacuum air degassing. Listing the choices which McIlvaine calls decisive classification is not that easy. For example, the next speaker explained why. Overview

 

Critical Measurements by Jean Holz of Hach 

 

Jean described which measurements were needed at each point in the boiler feedwater and condensate return system. When asked about optical vs. electrochemical choices, she replied that the range of choices depend on the point at which you are measuring and whether you need to measure a few ppb or some higher number. She observed that dissolved oxygen is measured in three accepted methods: Winkler Titration, Clark Cell Electrodes, and Luminescence-based Optodes.  LDO has proven to be the best choice except where you need to measure at very low levels. Hach supplies instruments to measure boiler feedwater quality.

 

FAC issues by Brad Buecher

 

Flow accelerated corrosion is an important issue causing problems in turbulent areas such as elbows. The condition occurs when steel is in contact with water with almost no oxygen. You must first take into account whether you are using any copper tubing.  If not you can raise the oxygen content slightly.

 

Activities of Ultrapure Water Magazine by Mike Henley

 

Ultrapure Water covers power as well as other ultrapure water applications. There are more than 1,000 archived articles.

 

Electrodeionization for Silica removal by Michael Snow of SnowPure

 

The choice of EDI plus membrane contactors is the way to deal with high silica content. You need the membrane contactors to reduce the CO2 rather than rely on EDI to achieve both tasks.  There are many such combinations on power plants in China. Michael observed that some of the Chinese power plants have the most extensive equipment while others have tried to minimize costs.

 

Coverage of Membrane Contactors by Bob Markle of Membrana

 

Membrane contactors provide CO2 reduction more cost effectively than forced deaerators. The advantages are the small footprint and high efficiency. The membrane prevents particulate in the sweep air from contaminating the water. With nitrogen sweep air very low oxygen levels can be achieved. http://www.mcilvainecompany.com/DegasDeminAnalysis/Subscriber/Default.htm

Click: (Subsidiary) Membrana

 

Time ran out on our 90 minute session and we did not have time to cover the use of UV for TOC removal.

 

Here are some articles which did not get posted in advance and the webinar participants with those companies. We will be posting these articles in the next few days.

 

Ø  Jeff Tate, Agape - Advantages of EDI

 

Ø  Mandeep Rayat, Eco-tec - Using municipal reclaimed water for 600 MW cc plants

Ø  David Gray, Mettler Toledo – Chemistry monitoring presentation from 2013 McIlvaine Webinar

Ø  Kaveh Someah, Ovivo - RO and IE in upgrading Dutch power plant

Ø  EPRI Guidelines for ACC -  (Does UPW change if you use ACC e.g., iron transport is higher)

 

The individual presentations follow:

Demineralization and Degasification Webinar - Hot Topic Hour August 28, 2014

Advantages of combining membrane contactors and EDI. Focus on the choices that need to be made by purchasers and operators of ultrapure water systems for gas turbine combined cycle power.

Revision Date:  8/28/2014

Tags:  221112 - Fossil Fuel 化石燃料, SnowPure, Ultrapure Water, Kiewit, Ultrapure Water, Membrane, EDI, Corrosion


Ultrapure Water Journal - Industrial Water Treatment by Mike Henley, Media Analytics Ltd. - Hot Topic Hour 8-28-14

Ultrapure Water covers power as well as other ultrapure water applications. There are more than 1,000 archived articles.

Revision Date:  8/28/2014

Tags:  221112 - Fossil Fuel 化石燃料, Ultrapure Water, Ultrapure Water, Oxygen, Demineralization


Control of Flow-Accelerated Corrosion in Steam Generators by Brad Buecher, Kiewit - Hot Topic Hour 8-28-14

Flow accelerated corrosion is an important issue causing problems in turbulent areas such as elbows.

Revision Date:  8/28/2014

Tags:  221112 - Fossil Fuel 化石燃料, Kiewit, Oxygen, Demineralization, Corrosion


Improving Silica Removal by EDI and GTM by Michael Snow, SnowPure

The choice of EDI plus membrane contactors is the way to deal with high silica content.

Revision Date:  8/28/2014

Tags:  221112 - Fossil Fuel 化石燃料, SnowPure, Membrane, EDI, Demineralization, Corrosion