Life after CAIR and CAMR was the Hot Topic on November 20, 2008
More than 60 people, many of them experts in their fields, participated in a good discussion of the status of PM2.5 and mercury regulations. Bob McIlvaine and Debbie Fox made presentations. Dave Foerter added insights and answered questions as well. Debbie is an environmental attorney and analyst at the McIlvaine Company. Dave is executive director of the Institute of Clean Air Companies.
Debbie traced the development of CAIR and CAMR and summarized the CAIR litigation status
There are a variety of fates for CAIR and CAMR
o CAIR rehearing or amended court decision?
o CAIR appeal to Supreme Court?
o Status of CAIR in the interim?
Participants seemed to agree that the greenhouse gas issue would impact the decisions on air pollutants. McIlvaine has been analyzing the eco-efficiency efforts of many companies and in particular the methods they use to determine eco-efficiency. The challenge is to quantify disparate categories such as air emissions, water pollution, resource consumption, global warming, etc. McIlvaine has made an attempt to quantify the combination of air pollution and global warming. The measurement is in tons of equivalent CO2.
CO2 EQUIVALENCY
Chemical |
CO2 Equivalent* |
Mercury |
10,000,000 |
Chromium Compounds |
1,000,000 |
Lead Compounds |
1,000,000 |
Arsenic |
1,000,000 |
Nickel Compounds |
100,000 |
Selenium Compounds |
100,000 |
Barium Compounds |
10,000 |
Zinc Compounds |
10,000 |
Vanadium Compounds |
10,000 |
Hydrochloric Acid |
1,000 |
Sulfuric Acid |
1,000 |
Hydrogen Fluoride |
1,000 |
Ammonia |
1,000 |
PM2.5 |
1,000 |
SO2 |
1,000 |
NOx |
100 |
CO2 |
1 |
*tons of CO2 per ton of each chemical compound
The basic method was to use the relative toxicity of each compound. EPA developed the Lesser Quantity Emission Rate (LQER). In turn this is derived from the Clean Air Act (CAA) listing of 10 tons as the threshold for the most benign air toxic e.g., hydrochloric acid. The LQER lists Vanadium at one ton and lead at 0.01 tons. Since the criteria pollutant threshold is 100 tons for NOx and SOx these were added to the list. Since NOx allowances are $2000/ton and CO2 allowances may be $20/ton, CO2 was added with an equivalent 100 x higher than NOx. It can be argued that CO2 should be $3/ton or $50/ton. So there is no absolute right or wrong equivalent. But it is unlikely that allowances will be higher than $20/ton for power plants in the foreseeable future. Based on the CO2 equivalents the pollution from all the coal plants has been determined.
U.S. COAL POWER CO2 EQUIVALENT EMISSIONS
Chemical |
CO2 Equivalent* |
US Emissions |
CO2 Equivalent |
Mercury |
10,000,000 |
0.05 |
500,000 |
Nickel Compounds |
100,000 |
0.35 |
35,000 |
Selenium Compounds |
100,000 |
0.215 |
21,500 |
Barium Compounds |
10,000 |
0.215 |
21,500 |
Zinc Compounds |
10,000 |
0.67 |
6,700 |
Vanadium Compounds |
10,000 |
0.615 |
6,150 |
Hydrochloric Acid |
1,000 |
267 |
267,000 |
Sulfuric Acid |
1,000 |
58 |
58,000 |
Hydrogen Fluoride |
1,000 |
28 |
28,000 |
Ammonia |
1,000 |
2.3 |
2,300 |
PM2.5 |
1,000 |
1,000 |
1,000,000 |
SO2 |
100 |
9,000 |
900,000 |
NOx |
100 |
4,000 |
400,000 |
CO2 |
1 |
2,000,000 |
2,000,000 |
Actual CO2 emissions are two billion tons/yr. Equivalent CO2 emissions from just the criteria pollutants are 2.3 billion tons equivalent. Toxic pollutants add more than one billion additional tons. (Only some of the toxics emitted by coal-fired power plants are included in the chart.) The conclusion is that there is more potential eco-efficiency in reducing air pollutants than in reducing CO2. The fact that it is also cheaper to reduce one ton of SO2 than 100 tons of CO2 is the other dimension in eco-efficiency.
These statistics cut both ways. A gas turbine compares better to a coal-fired power plant using the CO2 equivalents. But at gas prices above $6/MMBtu it would be better to spend the money cleaning up the existing coal-fired power plants than replacing them with gas-fired generators. Also a new coal-fired power plant with very low air pollution emissions, high efficiency and co-firing biomass could compare favorably to gas-fired power plants. For example, the lignite-fired Spiritwood power plant with 66 percent equivalent thermal efficiency due to the use of waste heat at the adjacent ethanol plant would have possibly even lower equivalent CO2 emissions than a gas-fired power plant.
The biggest revelation of this approach is that you cannot just simply compare coal to gas. A peaking single cycle gas turbine power plant might have only 30 percent thermal efficiency. A coal-fired power plant with BACT for all the air emissions could have a fraction of the CO2 equivalent ton release of a coal-fired power plant with no scrubber or SCR. But the CO2 equivalent emissions approach is a way to compare all these combinations.
We ended the session with more questions than answers. Here they are.